ZnSe-based II-VI crystals implanted with Transition Metals (TM)

II-VI compound forms predominantly cubic crystallographic structures. Ternary compound with a different atomic ration of magnesium, manganese and beryllium gives us the opportunity to change compound bandgap and lattice constant. Sets of (Zn,Mg)Se (Mg at.% ~5%) and (Zn,Mn,Be)Se (Mn at.% ~5%, Be at.% ~5%) crystals grown by modified Bridgman-Stockbarger method can be implanted with transition metals (TM) elements to check the influence of the crystal field of host material to energy levels of d-electrons. Additionally, optical constants (refractive index, extinction coefficient) can be modified selectively when implanted with TM due to split in spectroscopic terms. Chemical composition of obtained samples can be checked with XPS and PIXE methods. Host damage caused by ions implantation and electrical properties of implanted II-VI crystals are also important concerns.

Funded by

This project has no funding.


  • Sedzicki, P., Skowronski, L., Szczesny, R., Becker, H. W., Rogalla, D., Pawlak, M., & Derkowska-Zielinska, B.: Influence of phosphorus ion implantation on the optical properties of CdTe bulk crystal. Journal of Alloys and Compounds 2020 DOI: 10.1016/j.jallcom.2020.156002


This project has no theses.